Autors: Dochev, B. A., Dimova, D. P., Trojan K., Čapek J., Kamarska, K. V., Chuchulska B.
Title: Investigation of the Influence of Alloying Elements Ni, Cr, Co and Mo on the Crystallization Process, Phase Composition and Corrosion Resistance of AlSi25Cu4Cr and AlSi25Cu5Cr Alloys
Keywords: corrosion resistance, hypereutectic aluminum–silicon alloys, phase composition, thermal analysis

Abstract: To increase the mechanical and improve the operational properties of the AlSi25Cu4Cr and AlSi25Cu5Cr alloys, combinations of the alloying elements Ni, Co and Mo were used. The AlSi25Cu4Cr alloy was additionally alloyed with both Ni and Mo and Ni, Co and Mo, and the AlSi25Cu5Cr alloy was alloyed with Co and Mo in different concentrations. The dental alloys “wiron light” and “wironit” were used to introduce the elements Ni, Co, Mo, as well as additional amounts of Cr into the composition of the base compositions. The thermal analysis recorded a decrease in the liquidus and solidus temperatures of the base alloys, as well as a narrowing of their crystallization temperature range as a result of the added alloying elements. The influence of the used chemical elements on the phase composition of the alloys was established by X-ray diffraction. The elements Cr and Mo do not form secondary strengthening phases but dissolve in the α-solid solution. The results of the corrosion tests conducted in 1 M HCl solution and 1 M H2SO4 solution for 336 h and 504 h show that the elements Ni, Co and Mo improve the corrosion resistance of the alloys.

References

  1. Kandeva M. Dochev B. Dimova D. Zagorski M. Kasabov P. Investigation of the wear resistance of tribological systems composed of aluminium-silicon alloys: PART 1 J. Balk. Tribol. Assoc. 2024 30 59 66
  2. Kandeva M. Dochev B. Dimova D. Zagorski M. Kasabov P. Investigation of the wear resistance of tribological systems composed of aluminium-silicon alloys: PART 2 J. Balk. Tribol. Assoc. 2024 30 208 217
  3. Mahle GmbH Piston materials Pistons and Engine Testing. ATZ/MTZ-Fachbuch Vieweg+Teubner Verlag Wiesbaden, Germany 2012 10.1007/978-3-8348-8662-0_4
  4. Miladinović S. Stojanović B. Gajević S. Vencl A. Hypereutectic Aluminum Alloys and Composites: A Review Available online: https://link.springer.com/article/10.1007/s12633-022-02216-2 (accessed on 10 November 2022)
  5. Joseph O.O. Olubambi P.A. Joseph O.O. Edun B.M. Okeniyi J.O. Abioye O.P. Effects of Alloying on Aluminium-Silicon Alloys—A Review IOP Conf. Ser. Mater. Sci. Eng. 2021 1107 012116 10.1088/1757-899X/1107/1/012116
  6. Efzan M.N.E. Kong H.J. Kok C.K. Review: Effect of Alloying Element on Al-Si Alloys Adv. Mater. Res. 2013 845 355 359 10.4028/www.scientific.net/AMR.845.355
  7. Abalymov V.R. Zhereb V.P. Kleimenov Y.A. Antonov M.M. Effect of Heat Treatment on the Structure and Mechanical Properties of Eutectic Silumin Alloyed with Magnesium Met. Sci. Heat Treat. 2021 63 291 296 10.1007/s11041-021-00685-7
  8. Elsharkawi E.A. Ibrahim M.F. Samuel A.M. Doty H.W. Samuel F.H. Understanding the Effect of Be Addition on the Microstructure and Tensile Properties of Al–Si–Mg Cast Alloys Int. J. Met. 2022 16 1777 1795 10.1007/s40962-021-00715-3
  9. Liu X. Wang C. Zhang S. Song J. Zhou X. Zha M. Wang H. Fe-Bearing Phase Formation, Microstructure Evolution, and Mechanical Properties of Al-Mg-Si-Fe Alloy Fabricated by the Twin-Roll Casting Process J. Alloys Compd. 2021 886 161202 10.1016/j.jallcom.2021.161202
  10. Furui M. Kitamura T. Ishikawa T. Ikeno S. Saikawa S. Sakai N. Evaluation of Age Hardening Behavior Using Composite Rule and Microstructure Observation in Al-Si-Mg Alloy Castings Mater. Trans. 2011 52 1163 1167 10.2320/matertrans.MB201010
  11. Stanić D. Brodarac Z.Z. Li L. Influence of Copper Addition in AlSi7MgCu Alloy on Microstructure Development and Tensile Strength Improvement Metals 2020 10 1623 10.3390/met10121623
  12. Wang E.R. Hui X.D. Wang S.S. Zhao Y.F. Chen G.L. Improved Mechanical Properties in Cast Al-Si Alloys by Combined Alloying of Fe and Cu Mater. Sci. Eng. A 2010 527 7878 7884 10.1016/j.msea.2010.08.058
  13. Jeong C. High Temperature Mechanical Properties of AlSiMg-(Cu) Alloys for Automotive Cylinder Heads Mater. Trans. 2013 54 588 594 10.2320/matertrans.M2012285
  14. Bogdanoff T. Lattanzi L. Merlin M. Ghassemali E. Jarfors A.E.W. Seifeddine S. The Complex Interaction between Microstructural Features and Crack Evolution during Cyclic Testing in Heat-Treated Al–Si–Mg–Cu Cast Alloys Mater. Sci. Eng. A 2021 825 141930 10.1016/j.msea.2021.141930
  15. Lumley R.N. Gunasegaram D.R. Gershenzon M. O’Donnell R.G. Effect of Alloying Elements on Heat Treatment Response of Aluminium High Pressure Die Castings Int. Heat Treat. Surf. Eng. 2010 4 25 32 10.1179/174951409X12542264514004
  16. Pratheesh K. Ravi M. Kanjirathinkal A. Joseph M.A. Effects of Sr and Pressure on Microstructure, Mechanical and Wear Properties of near Eutectic Al–Si Piston Alloys Int. J. Cast Met. Res. 2015 28 301 309 10.1179/1743133615Y.0000000016
  17. Demirtaş H. Karakulak E. Babu N.H. Understanding the Effect of Ni Content on Microstructure and Mechanical Properties of A384 HPDC Alloy J. Alloys Compd. 2022 896 163111 10.1016/j.jallcom.2021.163111
  18. Lattanzi L. Giovanni M.T. Giovagnoli M. Fortini A. Merlin M. Casari D. Di Sabatino M. Cerri E. Garagnani G.L. Room Temperature Mechanical Properties of A356 Alloy with Ni Additions from 0.5 Wt to 2 Wt% Metals 2018 8 224 10.3390/met8040224
  19. Fedak M. Rimar M. Corny I. Kuna S. Experimental Study of Correlation of Mechanical Properties of Al-Si Casts Produced by Pressure Die Casting with Si/Fe/Mn Content and Their Mutual Mass Relations Adv. Mater. Sci. Eng. 2013 2013 585514 10.1155/2013/585714
  20. Ozyurek D. Yıldırım M. Yavuzer B. Simsek I. Tuncay T. The Effect of Ni Addition on Microstructure and Mechanical Properties of Cast A356 Alloy Modified with Sr Met. Mater. 2021 59 391 399 10.4149/km_2021_6_391
  21. Mbuya T.O. Odera B.O. Ng’ang’a S.P. Influence of Iron on Castability and Properties of Aluminium Silicon Alloys: Literature Review Int. J. Cast Met. Res. 2003 16 451 465 10.1080/13640461.2003.11819622
  22. Totten G.E. Tiryakioglu M. Kessler O. Encyclopedia of Aluminum and Its Alloys CRC Press Boca Raton, FL, USA 2019 10.1201/9781351045636
  23. Szymczak T. Gumienny G. Klimek L. Goły M. Szymszal J. Pacyniak T. Characteristics of Al-Si Alloys with High Melting Point Elements for High Pressure Die Casting Materials 2020 13 4861 10.3390/ma13214861
  24. Zhang L. Gao J. Damoah L. Robertson D.G. Removal of Iron from Aluminum: A Review Miner. Process. Extr. Metall. Rev. 2012 33 99 157 10.1080/08827508.2010.542211
  25. Hwang J.Y. Doty H.W. Kaufman M.J. The Effects of Mn Additions on the Microstructure and Mechanical Properties of Al-Si-Cu Casting Alloys Mater. Sci. Eng. A 2008 488 496 504 10.1016/j.msea.2007.12.026
  26. Taylor J.A. Iron-Containing Intermetallic Phases in Al-Si Based Casting Alloys Procedia Mater. Sci. 2012 1 19 33 10.1016/j.mspro.2012.06.004
  27. Švecová I. Tillová E. Kuchariková L. Knap V. Possibilities of Predicting Undesirable Iron Intermetallic Phases in Secondary Al-Alloys Transp. Res. Procedia 2021 55 797 804 10.1016/j.trpro.2021.07.047
  28. Dunn R. Aluminum Melting Problems and Their Influence on Furnace Selection Die Cast. Eng. B 1965 9 8 30
  29. Kumar L. Cheol J. Hui J. Kwang S.S. Effects of Cr and Ti Addition on Mechanical Properties and Thermal Conductivity of Al–7Si–3Mg Die-casting Alloys Met. Mater. Int. 2022 29 204 214 10.1007/s12540-022-01206-8
  30. Ling H. Shi H. Du X. Zan J. Liu J. Effect of Chromium Content on Microstructure and Properties of Casting Al-7Si-0.35Mg-0.02Sr Alloy Mater. Werkst. 2022 53 1229 1241 10.1002/mawe.202200071
  31. Liang Y. Cui C. Geng H. Liu L. Zhang S. Jin R. Synergistic Effects of Cr and Sr Addition on the Mechanical and Corrosion Properties of A356.2 Alloy Mater. Charact. 2022 191 112152 10.1016/j.matchar.2022.112152
  32. Li Y. Yang Y. Wu Y. Wei Z. Liu X. Supportive Strengthening Role of Cr-Rich Phase on Al-Si Multicomponent Piston Alloy at Elevated Temperature Mater. Sci. Eng. A 2011 528 4427 4430 10.1016/j.msea.2011.02.047
  33. Wang X. Ma P. Meng Z. Zhang S. Liu X. Wang C. Wang H. Effect of Trace Cr Alloying on Centerline Segregations in Sub-Rapid Solidified Al–Mg–Si (AA6061) Alloys Fabricated by Twin-Roll Casting Mater. Sci. Eng. A 2021 825 141896 10.1016/j.msea.2021.141896
  34. Kaufman J.G. Rooy E.L. Aluminum Alloy Castings: Properties, Processes, and Applications 1st ed. ASM International Amiel, The Netherlands 2004
  35. Lumley R.N. Fundamentals of Aluminium Metallurgy: Production, Processing and Applications Woodhead Publishing Suston, UK 2011
  36. Polmear I. StJohn D. Nie J.-F. Qian M. Light Alloys: Metallurgy of the Light Metals 5th ed. Elsevier Amsterdam, The Netherlands 2017
  37. Ganesh M.R.S. Reghunath N. Levin M.J. Prasad A. Doondi S. Shankar K.V. Strontium in Al–Si–Mg Alloy: A Review Met. Mater. Int. 2022 28 1 40 10.1007/s12540-021-01054-y
  38. Nafisi S. Ghomashchi R. Effects of Modification during Conventional and Semi-Solid Metal Processing of A356 Al-Si Alloy Mater. Sci. Eng. A 2006 415 273 285 10.1016/j.msea.2005.09.108
  39. Vincze F. Tokár M. Fegyverneki G. Gyarmati G. Examination of the Eutectic Modifying Effect of Sr on an Al-Si-Mg-Cu Alloy Using Various Technological Parameters Arch. Foundry Eng. 2020 2020 79 84 10.24425/afe.2020.133334
  40. Sigworth G.K. The Modification of Al-Si Casting Alloys: Important Practical and Theoretical Aspects Int. J. Met. 2008 2 19 40 10.1007/BF03355425
  41. Flores A.V. Lopez J.C. Escobedo J.C.B. Castillejos A.H.E. Acosta F.A.G. Effects of S and Sb Additions on the Microstructure and Mechanical Properties of the Al-Si 319 Alloy Can. Metall. Q. 1994 33 133 138 10.1179/cmq.1994.33.2.133
  42. Medlen D. Bolibruchova D. Effect of Sb-Modification on the Microstructure and Mechanical Properties of Secondary Alloy 319 Arch. Metall. Mater. 2016 61 553 558 10.1515/amm-2016-0095
  43. Zuo M. Zhao D. Teng X. Geng H. Zhang Z. Effect of P and Sr complex modification on Si phase in hypereutectic Al–30Si alloys Mater. Des. 2013 47 857 864 10.1016/j.matdes.2012.12.054
  44. Njuguna B. Li J. Tan Y. Sun Q. Li P. Grain refinement of primary silicon in hypereutectic Al-Si alloys by different P-containing compounds China Foundry 2021 18 37 44 10.1007/s41230-021-0074-2
  45. Guan R. Tie D. A review on grain refinement of aluminum alloys: Progresses, challenges and prospects Acta Metall. Sin. 2017 30 409 432 10.1007/s40195-017-0565-8
  46. Shi W. Gao B. Tu G. Li S. Effect of Nd on microstructure and wear resistance of hypereutectic Al–20%Si alloy J. Alloys Compd. 2010 508 480 485 10.1016/j.jallcom.2010.08.098
  47. Panov I. Dochev B. Manolov V. Velikov A. Diyakova V. Kuzmanov P. Investigation of the potential of simultaneous modification of hypereutectic aluminum-silicon AlSi18 alloy with conventional and nano-modifier IFAC-PapersOnLine 2019 52 488 493 10.1016/j.ifacol.2019.12.590
  48. Radev D. Tomova Z. Vlahova A. Marinov M. Kovacheva D. Comparative study on some structural properties of Ni- and Co base dental alloys produced by thermal alloying and powder metallurgical methods Mater. Today 2022 61 1265 1271 10.1016/j.matpr.2022.02.560
  49. Tomova Z. Chonin A. Stoeva I. Vlahova A. Clinical and laboratory study of corrosion resistance of a base dental alloy for selective laser melting Folia Med. 2023 65 664 670 10.3897/folmed.65.e73531 37655388
  50. Tomova Z. Vlahova A. Zlatev S. Stoeva I. Tomov D. Davcheva D. Hadzhigaev V. Clinical Evaluation of Corrosion Resistance, Ion Release, and Biocompatibility of CoCr Alloy for Metal-Ceramic Restorations Produced by CAD/CAM Technologies Dent. J. 2023 11 166 10.3390/dj11070166
  51. Kamarska K. Dimova D. Dochev B. Dubaradjieva M. Peeva N. Demirev T. Investigation of the Corrosion Resistance of Complex Alloyed Hypereutectic Aluminium-Silicon Alloys Proceedings of the 15th International Scientific Conference on Aeronautics, Automotive, and Railway Engineering and Technologies (BulTrans-2023) Sozopol, Bulgaria 22 February 2024 Volume 3129 10.1063/5.0201705
  52. Dochev B. Thermal analysis of aluminum-silicon alloys AlSi25Cu4Cr and AlSi25Cu5Cr modified with different phosphorus concentrations Proceedings of the National Youth Forum “SCIENCE, TECHNOLOGY, INNOVATIONS, BUSINESS” Plovdiv, Bulgaria 5–6 May 2022 116 122 (In Bulgarian)
  53. Dochev B. Dimova D. Panov I. Boichev Y. Investigation of the Structure and Mechanical Properties of Alloys AlSi25Cu4Cr and AlSi25Cu5Cr Alloyed with Refractory Metals Proceedings of the 15th International Scientific Conference on Aeronautics, Automotive, and Railway Engineering and Technologies (BulTrans-2023) Sozopol, Bulgaria 22 February 2024 Volume 3129 10.1063/5.0201703

Issue

Materials, vol. 18, 2025, Albania, https://doi.org/10.3390/ma18040907

Цитирания (Citation/s):
1. Dimova, D, Dochev, B, Trojan, K, Kamarska, K, Sofronov, Y, Zagorski, M, Tsonev, V, Nikolov, A, Investigation of the Structural, Mechanical and Operational Properties of an Alloy AlSi18Cu3CrMn, MATERIALS, vol 18, 2025, eissn: 1996-1944, art_no: ARTN 5434, doi: 10.3390/ma18235434, pmid: MEDLINE:41374276 - 2025 - в издания, индексирани в Web of Science

Вид: статия в списание, публикация в реферирано издание, индексирана в Scopus и Web of Science