Autors: Dochev, B. A., Sofronov, Y. P., Mishev, V. P., Nikolov, A. A., Petrov, K. L., Angelov M., Yordanov, M. G., Todorov, G. D., Marchev K. Title: Deposition of Multilayer Nanostructured Coating Cr/(Cr/a-C)ml on Alloy Steels Keywords: alloy steels, characteristics of Cr/(Cr/a-C)ml coating, nanolayered coating, nanostructured coatingAbstract: chromium/amorphous carbon (Cr/(Cr/a-C)ml) nanostructured multilayer coating with a chromium sublayer was deposited on 42CrMo4 (1.7225,BDS EN ISO 683-2:2018), 100Cr6 (1.3505, BDS EN ISO 683-17:2024), and HS18-0-1 (1.3355, BDS EN ISO 4957:2018) alloy steels, selected for their use in contact-loaded components subjected to cyclic fatigue and intense wear. The coating was sputter deposited by MF pulsed magnetron sputtering under consistent process parameters. The resulting coating, approximately 1.8 μm thick, can significantly enhance the service life of these components. Adhesion was evaluated via the Daimler–Benz test, while coating homogeneity was confirmed through energy-dispersive spectroscopy, revealing a consistent chemical composition across sample surfaces. Raman spectroscopy indicated a high sp3/sp2 ratio, confirming a dominant diamond-like carbon structure. Nanoindentation measurements verified the coating’s hardness, aligning with the observed structural properties. These results validate the process parameters for depositing a Cr/(Cr/a-C)ml coating on these alloy steels, achieving this study’s objectives. References - Hovsepian P. Kok Y. Ehiasarian A. Erdemir A. Wen J.-G. Petrov I. Structure and tribological behaviour of nanoscale multilayer C/Cr coatings deposited by the combined steered cathodic arc/unbalanced magnetron sputtering technique Thin Solid Films 2004 447–448 7 13 10.1016/j.tsf.2003.09.009
- Al Mahmud K.A.H. Kalam M.A. Masjuki H.H. Mobarak H.M. Zulkifli N.M. An updated overview of diamond-like carbon coating in tribology Crit. Rev. Solid State Mater. Sci. 2014 40 90 118 10.1080/10408436.2014.940441
- Liu S. Zhuang W. Ding J. Liu Y. Yu W. Yang Y. Liu X. Yuan J. Zheng J. Fabrication and Tribological Properties of Diamond-like Carbon Film with Cr Doping by High-Power Impulse Magnetron Sputtering Coatings 2024 14 916 10.3390/coatings14070916
- Gao Z. Buchinger J. Hahn R. Chen Z. Zhang Z. Koutná N. Mayrhofer P. Bilayer period and ratio dependent structure and mechanical properties of TiN/MoN superlattices Acta Mater. 2024 279 120313 10.1016/j.actamat.2024.120313
- Bertran E. Corbella C. Pinyol A. Vives M. Andújar J. Comparative study of metal/amorphous-carbon multilayer structures produced by magnetron sputtering Diam. Relat. Mater. 2003 12 1008 1012 10.1016/S0925-9635(02)00303-5
- Stueber M. Holleck H. Leiste H. Seemann K. Ulrich S. Ziebert C. Concepts for the design of advanced nanoscale PVD multilayer protective thin films J. Alloys Compd. 2009 483 321 333 10.1016/j.jallcom.2008.08.133
- Mao H. Shen F. Zhang Y. Wang J. Cui K. Wang H. Lv T. Fu T. Tan T. Microstructure and Mechanical Properties of Carbide Reinforced TiC-Based Ultra-High Temperature Ceramics: A Review Coatings 2021 11 1444 10.3390/coatings11121444
- Mao H. Zhang Y. Wang J. Cui K. Liu H. Yang J. Microstructure, Mechanical Properties, and Reinforcement Mechanism of Second-Phase Reinforced TiC-Based Composites: A Review Coatings 2022 12 801 10.3390/coatings12060801
- Ratayski U. Schimpf C. Schucknecht T. Mühle U. Baertz C. Leonhardt M. Scheibe H.-J. Rafaja D. On the Thermal Stability of Nanoscaled Cr/ta-C Multilayers SAXONIA Standortentwicklungs- und –verwaltungsgesellschaft mbH Freiberg, Germany 2015 184 199
- Hahn R. Bartosik M. Soler R. Kirchlechner C. Dehm G. Mayrhofer P. Superlattice effect for enhanced fracture toughness of hard coatings Scr. Mater. 2016 124 67 70 10.1016/j.scriptamat.2016.06.030
- Ul-Hamid A. Microstructure, properties and applications of Zr-carbide, Zr-nitride and Zr-carbonitride coatings: A review Mater. Adv. 2020 1 1012 1037 10.1039/D0MA00233J
- Ul-Hamid A. The effect of deposition conditions on the properties of Zr-carbide, Zr-nitride and Zr-carbonitride coatings—A review Mater. Adv. 2020 1 988 1011 10.1039/D0MA00232A
- Tao H. Zhylinski V. Vereschaka A. Chayeuski V. Yuanming H. Milovich F. Sotova C. Seleznev A. Salychits O. Comparison of the Mechanical Properties and Corrosion Resistance of the Cr-CrN, Ti-TiN, Zr-ZrN, and Mo-MoN Coatings Coatings 2023 13 750 10.3390/coatings13040750
- Koutná N. Brenner A. Holec D. Mayrhofer P.H. High-throughput first-principles search for ceramic superlattices with improved ductility and fracture resistance Acta Mater. 2021 206 116615 10.1016/j.actamat.2020.116615
- Bai H. Li J. Gao J. Ni J. Bai Y. Jian J. Zhao L. Bai B. Cai Z. He J. et al. Comparison of CrN Coatings Prepared Using High-Power Impulse Magnetron Sputtering and Direct Current Magnetron Sputtering Materials 2023 16 6303 10.3390/ma16186303 37763579
- Cunha L. Andritschky M. Pischow K. Wang Z. Microstructure of CrN coatings produced by PVD techniques Thin Solid Films 1999 355–356 465 471 10.1016/S0040-6090(99)00552-0
- Erdemir A. Martin J.M. Superior wear resistance of diamond and DLC coatings Curr. Opin. Solid State Mater. Sci. 2018 22 243 254 10.1016/j.cossms.2018.11.003
- Dalibón E. Escalada L. Simison S. Forsich C. Heim D. Brühl S. Mechanical and corrosion behavior of thick and soft DLC coatings Surf. Coat. Technol. 2017 312 101 109 10.1016/j.surfcoat.2016.10.006
- Ronkainen H. Varjus S. Holmberg K. Tribological performance of different DLC coatings in water-lubricated conditions Wear 2001 249 267 271 10.1016/S0043-1648(01)00561-0
- Sedlaček M. Podgornik B. Vižintin J. Tribological properties of DLC coatings and comparison with test results: Development of a database Mater. Charact. 2008 59 151 161 10.1016/j.matchar.2006.12.008
- Salvadori M. Martins D. Cattani M. DLC coating roughness as a function of film thickness Surf. Coat. Technol. 2006 200 5119 5122 10.1016/j.surfcoat.2005.05.030
- Manninen N. Ribeiro F. Escudeiro A. Polcar T. Carvalho S. Cavaleiro A. Influence of Ag content on mechanical and tribological behavior of DLC coatings Surf. Coat. Technol. 2013 232 440 446 10.1016/j.surfcoat.2013.05.048
- Azzi M. Amirault P. Paquette M. Klemberg-Sapieha J. Martinu L. Corrosion performance and mechanical stability of 316L/DLC coating system: Role of interlayers Surf. Coat. Technol. 2010 204 3986 3994 10.1016/j.surfcoat.2010.05.004
- Zia A.W. Anestopoulos I. Panayiotidis M.I. Birkett M. Soft diamond-like carbon coatings with superior biocompatibility for medical applications Ceram. Int. 2023 49 17203 17211 10.1016/j.ceramint.2023.02.085
- Kaneko M. Hiratsuka M. Alanazi A. Nakamori H. Namiki K. Hirakuri K. Surface Reformation of Medical Devices with DLC Coating Materials 2021 14 376 10.3390/ma14020376
- Malisz K. Świeczko-Żurek B. Sionkowska A. Preparation and Characterization of Diamond-like Carbon Coatings for Biomedical Applications—A Review Materials 2023 16 3420 10.3390/ma16093420
- Schalk N. Tkadletz M. Mitterer C. Hard coatings for cutting applications: Physical vs. chemical vapor deposition and future challenges for the coatings community Surf. Coatings Technol. 2022 429 127949 10.1016/j.surfcoat.2021.127949
- Ginting A. Skein R. Cuaca D. Herdianto Pieter Masyithah Z. The characteristics of CVD- and PVD-coated carbide tools in hard turning of AISI 4340 Measurement 2018 129 548 557 10.1016/j.measurement.2018.07.072
- Deng Y. Chen W. Li B. Wang C. Kuang T. Li Y. Physical vapor deposition technology for coated cutting tools: A review Ceram. Int. 2020 46 18373 18390 10.1016/j.ceramint.2020.04.168
- Kamiya S. Nagasawa H. Yamanobe K. Saka M. A comparative study of the mechanical strength of chemical vapor-deposited diamond and physical vapor-deposited hard coatings Thin Solid Films 2005 473 123 131 10.1016/j.tsf.2004.05.135
- Li X. Dai W. Wang Q. Liang Y. Wu Z. Diamond-like/graphite-like carbon composite films deposited by high-power impulse magnetron sputtering Diam. Relat. Mater. 2020 106 107818 10.1016/j.diamond.2020.107818
- Wang M. Liu Y. Chen H. Wang L. Hu D. First-Principles Calculations of Interfacial Structure and Properties between WC Substrate and TiN Coating Based on Density Functional Theory Coatings 2022 12 1076 10.3390/coatings12081076
- Yaqoob S. Ghani J.A. Jouini N. Juri A.Z. Performance Evaluation of PVD and CVD Multilayer-Coated Tools in Machining High-Strength Steel Coatings 2024 14 865 10.3390/coatings14070865
- Kucharska B. Czarniak P. Kulikowski K. Krawczyńska A. Rożniatowski K. Kubacki J. Szymanowski K. Panjan P. Sobiecki J.R. Comparison Study of PVD Coatings: TiN/AlTiN, TiN and TiAlSiN Used in Wood Machining Materials 2022 15 7159 10.3390/ma15207159
- Tien C.-L. Special Issue “Advanced Coating Technology by Physical Vapor Deposition and Applications” Coatings 2023 13 467 10.3390/coatings13020467
- Krella A. Resistance of PVD Coatings to Erosive and Wear Processes: A Review Coatings 2020 10 921 10.3390/coatings10100921
- Deng J. Wu F. Lian Y. Xing Y. Li S. Erosion wear of CrN, TiN, CrAlN, and TiAlN PVD nitride coatings Int. J. Refract. Met. Hard Mater. 2012 35 10 16 10.1016/j.ijrmhm.2012.03.002
- Zlamal T. Mrkvica I. Szotkowski T. Malotova S. The Influence of Surface Treatment of PVD Coating on Its Quality and Wear Resistant Coatings 2019 9 439 10.3390/coatings9070439
- D’Avico L. Beltrami R. Lecis N. Trasatti S.P. Corrosion Behavior and Surface Properties of PVD Coatings for Mold Technology Applications Coatings 2018 9 7 10.3390/coatings9010007
- Dabees S. Mirzaei S. Kaspar P. Holcman V. Sobola D. Characterization and Evaluation of Engineered Coating Techniques for Different Cutting Tools—Review Materials 2022 15 5633 10.3390/ma15165633
- Fox-Rabinovich G. Gershman I.S. Yamamoto K. Dosbaeva J. Veldhuis S. Effect of the Adaptive Response on the Wear Behavior of PVD and CVD Coated Cutting Tools during Machining with Built Up Edge Formation Nanomaterials 2020 10 2489 10.3390/nano10122489
- Džupon M. Kaščák Ľ. Spišák E. Kubík R. Majerníková J. Wear of Shaped Surfaces of PVD Coated Dies for Clinching Metals 2017 7 515 10.3390/met7110515
- BDS EN ISO 683-2:2018 Heat-Treatable Steels, Alloy Steels and Free-Cutting Steels—Part 2: Alloy Steels for Quenching and Tempering European Standard Brussels, Belgium 2018
- BDS EN ISO 683-17:2024 Heat-Treated Steels, Alloy Steels and Free-Cutting Steels—Part 17: Ball and Roller Bearing Steels European Standard Brussels, Belgium 2024
- BDS EN ISO 4957:2018 Tool Steels European Standard Brussels, Belgium 2018
- Gorman D. Green C. Fry T. Gee M. Rockwell Indentation Test for Evaluation of Adhesion of Coatings—Aka Daimler-Benz Adhesion Test National Physics Laboratory Report. MAT 107 NPL Management London, UK 2022 10.47120/npl.MAT107
- ISO 26423:2009 Fine Ceramics (Advanced CERAMICS, advanced Technical Ceramics)—Determination of Coating Thickness by Crater-Grinding Method International Standard Geneva, Switzerland 2009
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