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Автори: Славова, В. О., Митева М., Петров Ст. Заглавие: Modification by vacuum metallization of composite PAN membranes - conditions, mechanism and structure Ключови думи: ultrafiltration, vacuum metallization, polymer membrane Абстракт: Polyacrylonitrile ultrafiltration membranes obtained by phase inversion from 16 mass% solution of polyacrylonitrile (PAN) and dimethylsulfoxide (DMSO) were vacuum metalized for different exposition periods. It was found from the studies carried out on their selectivity (φ,%) and permeability (J, l/m2.h) towards water and calibrant, scanning electron microscopy (SEM) and atomic-force microscopy (AFM) that the metallization can successfully replace the thermal treatment used to stabilize the membrane structure during operation.
Depending on the metallization duration, metal layers of different densities and thicknesses were deposited which can be further used for modification of the selective and transport characteristics of the membrane. The optimal metallization time was determined to be 15 sec. with effective values of permeability – 33 l/m2.h and selectivity towards albumin – 80%. Библиография Издание
| Autors: Raykova, V. O., Miteva M., Petrov S. Title: Modification by vacuum metallization of composite PAN membranes - conditions, mechanism and structure Keywords: ultrafiltration, vacuum metallization, polymer membrane Abstract: Polyacrylonitrile ultrafiltration membranes obtained by phase inversion from 16 mass% solution of polyacrylonitrile (PAN) and dimethylsulfoxide (DMSO) were vacuum metalized for different exposition periods. It was found from the studies carried out on their selectivity (φ,%) and permeability (J, l/m2.h) towards water and calibrant, scanning electron microscopy (SEM) and atomic-force microscopy (AFM) that the metallization can successfully replace the thermal treatment used to stabilize the membrane structure during operation. Depending on the metallization duration, metal layers of different densities and thicknesses were deposited which can be further used for modification of the selective and transport characteristics of the membrane. The optimal metallization time was determined to be 15 sec. with effective values of permeability – 33 l/m2.h and selectivity towards albumin – 80%. References Issue
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