Autors: Gospodinova, D. N., Shopov, M. D.
Title: Influence of Collector Geometry on the Morphology of Electrospun Fibers
Keywords: collector geometry, electrospinning, electrospun fibers, nanofiber morphology, plasma treatment

Abstract: This study investigates the influence of collector geometry and surface treatment on the morphology of electrospun polyvinyl alcohol (PVA) nanofibers. Three collector configurations differing in electrode arrangement and surface area were evaluated using a consistent electrospinning setup that included a denim dielectric barrier. One of the collectors was additionally treated with cold atmospheric plasma to examine the effects of surface modification. Key process parameters, including operating voltage, electrical conductivity, and spinneret-to-collector distance, were systematically controlled. The resulting fiber mats were analyzed using scanning electron microscopy (SEM) and atomic force microscopy (AFM) to assess fiber diameter distribution, surface uniformity, and defect density. The results show that collector geometry significantly affects electric field distribution and fiber formation: the fully conductive Type I collector yielded the most uniform and defect-free fibers, while the dual-electrode and plasma-treated configuration led to increased variability and structural imperfections. These findings underscore the critical role of collector design in optimizing nanofiber morphology for applications in filtration, biomedical devices, and advanced textiles.

References

  1. J. Xue, T. Wu, Y. Dai, and Y. Xia, "Electrospinning and Electrospun Nanofibers: Methods, Materials, and Applications, " Chem. Rev., vol. 119, no. 8, pp. 5298-5415, Apr. 2019, doi: 10.1021/acs.chemrev.8b00593.
  2. M. Afshari, Electrospun nanofibers. in Woodhead publishing series in textiles, no. number 186. Duxford, United Kingdom: Woodhead Publishing, 2017.
  3. R. Asmatulu and W. S. Khan, Synthesis and applications of electrospun nanofibers. in Micro & nano technologies series. Kidlington, Oxford Cambridge, MA: Elsevier, 2019.
  4. T. Lin, Fundamentals of electrospinning & electrospun nanofibers, 1st edition. Lancaster, PA: DEStech Publications, Inc, 2016.
  5. L. Wang and X. Qin, Eds., Electrospinning: Fundamentals, methods, and applications. Weinheim: Wiley-VCH, 2024.
  6. L. M. Valencia-Osorio, M. L. Aguiar, and M. L. Álvarez-Láinez, " Electrospinnability and Air Filtration Efficiency of PVDF Nanofibers: The Role of Electrospinning Solution Properties, " J of Applied Polymer Sci, p. e56613, Dec. 2024, doi: 10.1002/app. 56613.
  7. N. Aminu et al., "Applications of nanofibers drug delivery system in cancer therapy, " Journal of Drug Delivery Science and Technology, vol. 90, p. 105128, Dec. 2023, doi: 10.1016/j.jddst.2023.105128.
  8. M. Shopov, "Electrical Process Parameters of Electrospinning, " in 2024 16th Electrical Engineering Faculty Conference (BulEF), Varna, Bulgaria: IEEE, Sep. 2024, pp. 1-6. doi: 10.1109/BulEF63204.2024.10794870.
  9. A. A. Fridman, Plasma chemistry, First paperback edition. Cambridge: Cambridge University Press, 2012.
  10. S. Thomas, Ed., Non-thermal plasma technology for polymeric materials: Applications in composites, nanostructured materials and biomedical fields. Cambridge, MA: Elsevier, 2019.
  11. T. Lin and J. Fang, Fundamentals of electrospinning & electrospun nanofibers. Lancaster, Pennsylvania: DEStech Publications, Inc, 2017.
  12. L. Wang and X. Qin, Eds., Electrospinning: Fundamentals, methods, and applications. Weinheim: Wiley-VCH, 2024.
  13. R. Bhattarai, R. Bachu, S. Boddu, and S. Bhaduri, "Biomedical Applications of Electrospun Nanofibers: Drug and Nanoparticle Delivery, " Pharmaceutics, vol. 11, no. 1, p. 5, Dec. 2018, doi: 10.3390/pharmaceutics11010005.
  14. Y. Huang, Y. Li, Y. Zhang, H. Yu, and Z. Tan, "Near-field electrospinning for 2D and 3D structuring: Fundamentals, methods, and applications, " Materials Today Advances, vol. 21, p. 100461, Mar. 2024, doi: 10.1016/j.mtadv.2023.100461

Issue

2025 19th International Conference on Electrical Machines, Drives and Power Systems, ELMA 2025 - Proceedings, 2025, Albania, https://doi.org/10.1109/ELMA65795.2025.11083458

Вид: публикация в международен форум, публикация в реферирано издание, индексирана в Scopus