Autors: Petrova M., Lazarova D., Dobrev D., Georgieva, M. G., Petrova S.
Title: Development of an environmentally friendly pre-treatment for electroless metallisation of glasses
Keywords: APTS, copper coatings, electroless deposition, Environmentally friendly, glass samples, nickel-phosphorus coatings, pre-treatment, wetting contact angle

Abstract: In recent years, the growing need for materials that have high thermal resistance, non-flammability, high radioactive resistance and durability is the reason for the development of new technologies for electroless metallisation of glasses. The most important operation is surface roughening, which is usually carried out in etching solutions containing HF acid, which is harmful to the environment and to health and safety at work. In this regard, the aim of the present research is the creation of an environmentally friendly technology for electroless metallisation of glasses. Тhe samples were pre-treated in two ways: one group was covered with a thin polymer film (Plastik 70 special glue or epoxy resin, thinned with dimethylformamide), and the other was degreased and treated with a solution of (3 aminopropyl) trimethoxysilane (APTS) at different concentrations and under different conditions. All samples were activated with a colloidal activator, after which copper or nickel-phosphorus coatings were deposited by electroless plating.

References

  1. V. K., Bajpai, H., Pandey, T., Singh and P., Dixit: Ultrasonic-assisted surface roughening of glass samples to improve adhesion of electroless nickel seed layer in microsystems packaging. Mater. Lett., 2022, 316, Article 132033.
  2. R., Muraliraja, R. A. S., Selvan, A., Selvakumar, M., Franco, T. R., Tamilarasan, U., Sanjith, W., Sha and J., Sudagar: A review of electroless coatings on non-metals: Bath conditions, properties and applications. J. Alloys Compds., 2023, 960, Article 170723.
  3. T. L., Chiang, A. Y., Cheng, J. L., You, C. P., Chang and M. D., Ger: Efficient copper plating on glass samples through amine-functionalized nanocomposite-immobilized silver nanoparticles. Colloids Surf. A: Physicochem. Eng. Aspects, 2024, 688, Article 133581.
  4. M., Charbonnier and M., Romand: Tin-free electroless metallization of glass samples using different PACVD surface treatment process. Surf. Coat. Technol., 2003, 162(1), 19–30.
  5. B. K. W., Baylis, A., Busuttil, N. E., Hedgecock and M., Schlesinger: Tin (IV) chloride solution as a sensitizer in photoselective metal deposition. J. Electrochem. Soc., 1976, 123(3), 348–351.
  6. H., Honma and K., Kanemitsu: Electroless nickel plating on alumina ceramics. Plat. Surf. Finish., 1987, 74(9), 62–66.
  7. C. E., Baumgartner: Adhesion of Electrolessly Deposited Nickel on Lead Zirconate Titanate Ceramic. J. Amer. Ceram. Soc., 1989, 72(6), 890–895.
  8. W., Su, L., Yau, F., Yang, P., Li, J., Chen and L., Liang: Electroless plating of Copper on surface modified glass samples. Appl. Surf. Sci., 2011, 257, 8067–8071.
  9. X., Cui, D. A., Hutt and P. P., Conway: Evolution of microstructure and electrical conductivity of electroless copper deposits on a glass sample. Thin Solid Films, 2012, 520(19), 6095–6099.
  10. H., Honma, K., Oyamada and I., Koiwa: Advanced plating technology for electronic devices. Electrochem., 2006, 74(1), 2–11.
  11. B., Tzaneva, E., Dobreva, N., Koteva, M., Georgieva and M., Petrova: Effect of etching conditions on electroless Ni-P plating of 3D printed PLA. Trans. IMF, 2022, 100(3), 166–172.
  12. ASTM D4541-02. “Standard test method for pull-off strength of coatings using portable adhesion testers”.
  13. B., Vasconcelos, R., Serra, J., Oliveira and C., Fonseca: Electroless deposition of Ni-P coatings on HNBR for low friction rubber seals. Coatings, 2020, 10(12), Article 1237).
  14. M., Schena: ‘Microarray analysis’, (ed. Z., Liang), 86–108; 2004, Beijing, Science Publishing Company.
  15. M., Qin, S., Hou, L. K., Wang, X. Z., Feng, R., Wang, Y. L., Yang, C., Wang, L., Yu, B., Shao and M. Q., Qiao: Qiao: Two methods for glass surface modification and their application in protein immobilization. Colloids Surf. B: Biointerfaces, 2007, 60(2), 243–249.

Issue

Transactions of the Institute of Metal Finishing, pp. 26-32, 2024, United Kingdom, https://doi.org/10.1080/00202967.2024.2426370

Цитирания (Citation/s):
1. Pawar K., Dixit P., Synergistic enhancement of electroless film adhesion on glass via graphene-oxide functionalization and surface roughening, 2025, Materials Letters, issue 0, vol. 400, DOI 10.1016/j.matlet.2025.139192, issn 0167577X, eissn 18734979 - 2025 - в издания, индексирани в Scopus и/или Web of Science

Вид: статия в списание, публикация в издание с импакт фактор, публикация в реферирано издание, индексирана в Scopus и Web of Science